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The authors consider that the extended system and lower symmetric structure of the C 70 fullerene cage, which possess higher activated electron-deficient areas on the cage surface, can extremely quench various free radicals ( The typical representative of the metallofullerene family is Gd@C 82 , while gadolinium endohedral metallofullerenol comprises a functionalized C 82 fullerene cage with metal trapped inside ( 70 fullerenes reveal higher scavenging activity than L-alanine modified C 70 fullerene ( 60 -PDA-GSH are rationally designed and synthesized, and their relative cytoprotective effects against oxidative stress provide a candidate for the treatment of ROS-related diseases ( 60 is modified by the self-polymerization of dopamine into C 60 -PDA hybrids